She lives with her mummy and daddy, and twin little sisters named Zuzu & Zaza Zebra. Her favorite toy is a stuffed Monkey, who she treats as a pet, but has no problem admitting he isn't real.
Zoë is a white zebra with stripes of black over her left eye, right ear and, the back of her head. A single ring of white circles her arms, while her hands and tail are entirely black. She has a rounded pink nose. She wears the same black shoes as the other characters and a violet dress.
Zoë is a friendly Zebra who appears to be generally nice and a bit quiet. But, she sometimes doesn't pay attention to others and can misbehave in her own environment; as shown when she changed the Television without asking Daddy Zebra's permission, or not allowing Zuzu and Zaza to join her slumber party until the other girls convinced her they can stay in the sitting room. However, she seems to get along well with her little sisters, and friends compared to Peppa's relationship with George.